近20年太湖流域典型区土壤养分时空变化及驱动机理

长期的定位采样试验研究了近 2 0年锡山市甘露乡土壤表层 ( 0～ 2 0cm)中有机质、全氮、速效氮、速效磷、速效钾等土壤养分的时空变化趋势 ,并分析了土壤养分波动与国家政策、耕作方式、农业投入和单位面积农业纯收益之间的相互关系。结果表明 :2 0年间土壤养分质量总体上呈现先减后增的变化趋势。有机质呈现先减后增的变化趋势 ,且与耕作措施的改变有密切关系。全氮和速效氮呈持续上升趋势 ,上升幅度大于 1 0 0 % ,与氮肥使用量不断上升密切相关。速效磷、速效钾呈持续下降趋势 ,与磷肥、钾肥使用过少有关。国家政策和耕作方式、种植制度对SNQI影响十分明显 ,标准农业投入与土壤养分质量指数呈正相关关系 ,单位面积标准农业纯收益与土壤养分质量指数呈负相关关系     

Partitioning characteristics of PAHs between sediment and water in a shallow lake

Goal, Scope and Background

Distribution of hydrophobic organic contaminants in abiotic compartments is essential for describing their transfer and fate in aquatic ecosystems. Taihu Lake is the third largest freshwater lake in China. Water quality of Taihu Lake has deteriorated greatly during the last decades and has threatened the water supply. The aim of the present study was to investigate the partitioning of polycyclic aromatic hydrocarbons (PAHs) among overlying water, suspended particulate matter (SPM), sediments, and pore water in Meiliang Bay, Taihu Lake and to provide useful information for the ecological engineering in this area.

Materials and Methods

Overlying water and surface sediment were sampled from six sites in Meiliang Bay, Taihu Lake, China. Within 72 h of sampling, sediments were centrifuged to obtain the pore water. Overlying water samples were filtered to separate dissolved and SPM samples. After extraction, samples were purified following a clean-up procedure. PAH fraction was obtained by elution with a mixture of hexane: DCM (7:3, V/V) and analyzed by GC/MS.

Results

PAHs concentrations in overlying water varied from 37.5 ng/L to 183.5 ng/L. Concentrations of PAHs in pore water were higher than those in overlying water. The total concentrations of 16 priority PAHs in sediments ranged from 2091.8 ng/g-dw to 4094.4 ng/g-dw. PAHs concentrations on SPM were decreased with suspended solid concentrations (SSC). Total PAHs concentrations on SPM varied in the range of 3369.6 ng/g-dw to 7531.1 ng/g-dw. The partition coefficients between sediment and overlying water (log K _oc) for PAHs with log K _ow<5 were positively correlated with their octanol-water partition coefficients (log K _ow) (n=39, r=0.79, p<0.0001). Partition coefficients between sediment and pore water (log K _oc′) for all PAHs were also significantly correlated with their log K _ow values (n=48, r=0.82, p<0.0001).

Discussion

In general, PAHs derived from combustion sources tend to bind strongly to soot particles in natural sediment. Consequentially, K _oc values observed in the natural environment could be orders of magnitude higher than those predicted by linear correlation relationships under laboratory conditions. In the present study, the ratio of log K _oc values to log K _ow values falls consistently above 1, indicating that the sediment soot carbon in the bay was more attractive for PAHs than n-octanol. The log K _oc′ was also higher than that predicted under laboratory conditions, suggesting that the measured pore water PAH concentrations were lower than those predicted. That is to say, not all the sediment PAHs can be available to partition rapidly into sediment pore waters. A variation in soot content is a possible reason. Furthermore, concentrations of PAHs on SPM were higher than those in sediments. The compositions of PAHs on SPM and in sediments were similar, indicating the importance of re-suspension process of sediments in the partitioning process of the shallow lake.

Conclusions

The results indicated the equilibrium partitioning model could be used to predict PAHs distribution in various phases of a shallow lake in the stagnation period, but re-suspension processes should be considered to modify the relationship between log K _ocs and log K _ows.

Recommendations and Perspectives

Concentration, particle size and composition of resuspended particles could affect the relationship between log K _ocs and log K _ows. Further work should be done under field conditions, especially where a steady thermodynamic equilibrium state could be assumed.

     

芜湖市镜湖底泥TN、TP、重金属污染及其对上覆水体的影响

采集镜湖底泥及水样,研究底泥中重金属的污染现状,分析底泥TN、TP重金属与上覆水体相同成分的相关性,结果表明：（1）镜湖底泥TN、TP与水体TN、TP含量呈有著相关性,底泥N？P释放再悬浮是镜湖水体TN、TP来源之一。（2）镜湖除Cd严重超标外,Cu？Zn？Pb含量都很低;Cd（n）与Cd（w）有较好的负相关性,Cu（n）与Cu（w）？Zn（n）与Zn（w）？Pb（n）与Pb（w）相关性差。本研究为有关部门治理和管理镜湖提供理论依据。     

巢湖流域土地利用程度变化及其空间异质性分析

基于GIS和遥感平台提取巢湖流域范围,分析了2000-2013近15年来的巢湖流域土地利用程度及其空间异质性特征。研究表明:①近15年来,巢湖流域的土地利用结构变化较大,呈现"三减一增"的变化趋势,即林地、农地和水体呈下降趋势,建设用地呈上升趋势,其中,农地面积下降明显,建设用地面积增幅较大;②土地利用程度变化两极分化,弱土地利用程度显著下降,强土地利用程度明显增加。分析表明,2000—2013年的近15年间,弱和较弱土地利用程度的流域面积下降3 429 km~2,占总流域面积24.61%;较强和强土地利用程度的流域面积上升729 km~2,占总流域面积5.23%;③土地利用程度空间异质性分析表明,2000年和2013年巢湖流域土地利用程度全局空间自相关的Moran's I值分别为0.802 2和0.753 9,呈显著的正相关关系,表明巢湖流域土地利用程度不是无序的,而是具有明显的空间集聚性;局部空间自相关分析表明,LISA图显示土地利用程度的高高值区主要集聚在以合肥市区为核心的周围,低低值区主要集聚在以西南部的大别山森林地区和中部巢湖及沿湖周边。     

基于TM影像的升金湖湿地生态安全研究

[目的]分析安徽省升金湖湿地景观格局动态变化过程,建立升金湖湿地生态安全(PSR)模型,并探讨其驱动力,为进一步开展升金湖湿地保护及其恢复研究提供科学依据。[方法]在遥感和GIS技术支持下,用1986,2003,2011年的3期TM影像为基本信息源进行分析。[结果]景观格局变化幅度较大,草地和水域面积减幅较显著;多样性指数呈上升趋势而优势度指数呈下降趋势,破碎化程度加剧,斑块类型呈多样性发展;随着景观破碎化程度增强,斑块数增加,将造成湿地生态系统片断化越严重,也会影响到湿地的调蓄能力,改变整个湿地的水文情势,减弱湿地的生态效益;另外,景观格局变化下的湿地生态安全指数趋于逐年下降状态,湿地生态安全形式处于预警状态,形势不容乐观。[结论]近年来,随着经济的发展,人口数量的增加,围垦等活动的加剧,人类活动对研究区的改造导致了自然湿地面积相对减少,升金湖湿地生态功能不断下降,经济增长和人口增长成为湿地格局变化主要驱动力。     

Lakeshore diversity and rarity relationships along interacting disturbance gradients: catchment area, wave action and depth

Diversity patterns of riparian plant communities have been associated with disturbance. Populations of a diversity of Atlantic Coastal Plain plants occur as disjuncts on shores of large catchment area lakes in Nova Scotia. These lakeshore communities contain rare plants with local, national and global rankings. The populations of rare plants are dynamic and their management requires an understanding of the relationship between disturbance and the survival of rare plants. This present study measured (overwinter wooden dowel removal) and observed disturbance along gradients of catchment area (CA), exposure and depth. In three separate experiments ranging from the landscape to the lake, to the single shoreline level, disturbance was linked to lake CA, exposure and depth, respectively. At all scales, disturbance was positively associated with the presence of rare species. The pattern of rare species richness over the river system was complex; at the within-lake level, the frequency of rare species per site was greatest in the intermediate CA lake while the pool of rare species was greatest in the largest CA lake. The findings focus field efforts on wide, exposed shorelines of large CA lakes where new rare plants continue to be discovered. In addition, the discrepancy between highest frequency of rare plants on intermediate CA lakes and highest species pools of rarities on large CA lakes, reinforces the need for larger protected area systems for the most naturally disturbed ecosystems which often support populations having a high turnover rate but a low site to site frequency.     

江西水土流失对防洪的影响及防治对策

江西省水土流失面积 3 5 2万km2 ,严重破坏了生态环境。水土流失导致河床和水库淤积 ,加剧了洪涝灾害程度。鄱阳湖承担着长江巨大超额洪水的调蓄 ,但湖区面积已由 2 0世纪 5 0年代初期的 5 10 0多km2 萎缩到现在的 3 95 0多km2 ,容积缩小了 72亿m3。本省境内的“五河”流入鄱阳湖内的水量达 14 0 0多亿m3,是该湖容积的 4倍多 ,可见搞好水土保持对长江防洪的重要意义。水土保持措施已在防洪减灾中发挥了重大作用 ,应把水土保持生态环境建设作为长江和本省新世纪水利发展战略的重要内容     

基于水量调控防治艾比湖流域沙尘天气灾害的设想

针对艾比湖流域生态环境灾害，分析其成灾原因及发生规律。从改变水量分配时间格局的角度，分析入湖水量季节调控的可行性并提出实施方案。具体为通过人工引、蓄水设施将秋、冬季入湖地表径流蓄积起来，在春季大风、沙尘多发季节注入湖中，减少此时沙尘天气的发生。确定春季所需补充的水量，先以湖区地形图为基础建立湖区数字高程矩阵，然后回归计算湖面面积与湖水体积对应函数，此时根据实测的当年春季湖面面积即可算出达到预定湖面面积所需水量。按照此方案修建人工引、蓄水设施并实施调控后，既可以治理流域沙尘天气，又可最大限度节省水资源。     

洞庭湖区乡村人居环境质量动态评价及障碍因子诊断

为探索乡村人居环境质量的演变规律，该研究综合运用遥感影像、兴趣点、统计数据等多源数据，从生产空间、生活空间、生态空间3个维度构建了乡村人居环境质量评价指标体系，采用熵值法、综合指数法和GIS空间分析对2010—2020年洞庭湖区乡村人居环境质量开展了动态评价，并利用障碍度模型诊断了主要障碍因子。结果表明：1）2010—2020年洞庭湖区乡村人居环境建设成效明显，但区域之间仍存在较大差异，其人居环境质量综合指数在空间上呈现西南部相对下降，东北部逐渐上升的演变趋势；2）从乡村人居环境系统内部来看，2010—2020年生产空间质量指数稳定上升，较高及以上质量等级县域的分布已从洞庭湖区南部转向东部，空间格局发生较大变化；生活空间质量指数明显提高，呈现由市辖区逐渐向外扩张发展的空间演变规律；生态空间质量指数基本保持不变，空间上呈现顺序为西部地区、东部地区、中部地区梯度递减的分布特征；3）影响洞庭湖区乡村人居环境质量的主要障碍因子为乡村经济活动强度、生物丰富度指数、乡村休闲设施密度、农业机械化水平、乡村电力设施水平、医疗情况和水文指数。研究结果一定程度上充实、丰富了乡村人居环境质量理论成果，同时也为推进洞庭湖区乡村人居环境质量提升和乡村振兴状态监测提供了数据与决策支撑。     

淹水时间对水稻土磷素形态转化及其有效性的影响

水稻土淹水后土壤中P的形态及其有效性发生了变化,为掌握淹水时间对这种变化影响的规律,选择太湖地区典型水稻土-黄泥土为试验样本,在室内进行了不同淹水时间的土壤培育试验,并采用新鲜土壤样品测定的方法,研究了淹水时间对土壤P素形态转化及其有效性的影响.结果表明:①淹水时间主要影响Fe-P、O-P、Ca10-P和Ca8-P的转化.与淹水前相比,淹水使Fe-P和Ca8-P增加、O-P和Ca10-P减少,其中,Fe-P和Ca8-P分别于淹水45和15天后增加最为显著并趋于稳定,此时分别增加了194和9.6 mg/kg(分别占淹水前的93％和73％);O-P和Ca10-P于淹水15天后减少最为显著并趋于稳定,此时分别减少了72和20 mg/kg(分别占淹水前的24％和27％):②淹水改变了水稻土P素有效性及有效P的数量,与淹水前相比,淹水45天,水稻土 P素有效性及有效P的数量最高,有效P增加了32 mg/kg(占淹水前的57％).结论:淹水时间影响着水稻土 P素形态转化、有效性以及有效P的数量,淹水45天,水稻土P素形态转化数量最大、有效性最高和有效P的数量最大.